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Fick's laws of diffusion

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Fick's laws of diffusion describe diffusion and were derived by Adolf Fick in They can be used to solve for the diffusion coefficient , D. Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation. Fick's first law relates the diffusive flux to the concentration under the assumption of steady state. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient spatial derivative , or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low concentration across a concentration gradient.

In one spatial dimension, the law is:. D is proportional to the squared velocity of the diffusing particles, which depends on the temperature, viscosity of the fluid and the size of the particles according to the Stokes-Einstein relation. In dilute aqueous solutions the diffusion coefficients of most ions are similar and have values that at room temperature are in the range of 0.

In chemical systems other than ideal solutions or mixtures, the driving force for diffusion of each species is the gradient of chemical potential of this species.

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